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Space-faring crews must have safe breathing air throughout their missions to ensure adequate performance and good health. Toxicological assessment of air quality depends on the standards that define acceptable air quality, measurements of pollutant levels during the flight, and reports from the crew on their in-flight perceptions of air quality. Air samples returned from ISS on flights 8A, UF2, 9A, and 11A were analyzed for trace pollutants. On average, the air during this period of operations was safe for human respiration. However, about 3 hours into the regeneration of 2 Metox canisters in the U.S. airlock on 20 February 2002 the crew reported an intolerable odor that caused them to stop the regeneration, take refuge in the Russian segment, and scrub air in the U.S. segment for 30 hours. Analytical data from grab samples taken during the incident showed that the pollutants released were characteristic of nominal air pollutants, but were present in much higher concentrations.

The Major Constituent Analyzer (MCA) was activated on-orbit on 2/13/01 and provided essentially continuous readings of partial pressures for oxygen, nitrogen, carbon dioxide, methane, hydrogen and water in the ISS atmosphere. The MCA plays a crucial role in the operation of the Laboratory ECLSS and EVA operations from the airlock. This paper discusses the performance of the MCA as compared to specified accuracy requirements. The MCA has an on-board self-calibration capability and the frequency of this calibration could be relaxed with the level of instrument stability observed on-orbit. This paper also discusses anomalies the MCA experienced during the first year of on-orbit operation. Extensive Built In Test (BIT) and fault isolation capabilities proved to be invaluable in isolating the causes of anomalies. The process of fault isolation is discussed along with development of workaround solutions and implementation of permanent on-orbit corrections.

There are many sources of air pollution that can threaten air quality during space missions. The International Space Station (ISS) is an extremely complex platform that depends on a multi-tiered strategy to control the risk of excessive air pollution. During the seven missions surveyed by this report, the ISS atmosphere was in a safe, steady-state condition; however, there were minor loads added as new modules were attached. There was a series of leaks of octafluoropropane, which is not directly toxic to humans, but did cause changes in air purification operations that disrupted the steady state condition. In addition, off-nominal regeneration of metal oxide canisters used during extravehicular activity caused a serious pollution incident.

Future spacesuits will require thermal insulation protection in low-earth orbit (LEO), in the near-earth neighborhood and in planetary environments. In order to satisfy all future exploration needs and lower production and maintenance costs, a common thermal insulation is desirable that will perform well in all these environments. A highly promising material is a fiber-reinforced aerogel composite insulation currently being developed at the Johnson Space Center. This paper presents an overview of aerogels and their manufacture, a summary of the development of a flexible fiber-based aerogel for NASA by Aspen Aerogels, Inc., and performance data of aerogels relative to flexible commercial insulation. Finally, future plans are presented of how an aerogel-based insulation may be integrated into a spacesuit for ground testing as well as for a flight configuration.

For planetary exploration, new thermal insulation materials are needed to deal with unique environmental conditions presented to extravehicular activity (EVA). The thermal insulation material and system used in the existing space suit were specifically designed for low orbit environment. They are not adequate for low vacuum condition commonly found in planetary environments with a gas atmosphere. This study attempts to identify the types of lofty nonwoven thermal insulation materials and the construction parameters that yield the best performance for such application. Lofty nonwovens with different construction parameters are evaluated for their thermal conductivity performance. Three different types of fiber material: solid round fiber, hollow fiber, and grooved fiber, with various denier, needling intensity, and web density were evaluated.

Humidity condensate collected and processed in-flight is an important component of a space station drinking water supply. Water recovery systems in general are designed to handle finite concentrations of specific chemical components. Previous analyses of condensate derived from spacecraft and ground sources showed considerable variation in composition. Consequently, an investigation was conducted to collect condensate on the Shuttle while the vehicle was docked to Mir, and return the condensate to Earth for testing. This scenario emulates an early ISS configuration during a Shuttle docking, because the atmospheres intermix during docking and the condensate composition should reflect that. During the STS-89 and STS-91 flights, a total volume of 50 liters of condensate was collected and returned. Inorganic and organic chemical analyses were performed on aliquots of the fluid.

Gas transfer systems in a closed life support test were controlled by intelligent layered monitoring and control software. Interactive simulation-based testing was used for system-level validation of the discrete sequencer layer of the software. An advanced discrete event simulation tool was used to model diverse components and systems for processing gases in a plant growth chamber, crew chamber and incinerator, and transferring gases between chambers. Models included physico-chemical and biological gas processors, pumps, concentrators, chambers and tanks, and devices for configuring and controlling gas transfer. Several types of control were modeled. This paper describes the models, the testing approach, and some results of the testing.

Scientists and engineers at NASA are currently developing flight instruments which will demonstrate oxygen production on the Moon and Mars. REGA will extract oxygen from the lunar regolith, measure implanted solar wind and indigenous gases, and monitor the lunar atmosphere. MIP will demonstrate oxygen production on Mars, along with key supporting technologies including filtration, atmospheric acquisition and compression, thermal management, solar cell performance, and dust removal.

The Flash Evaporator Subsystem (FES) provides active cooling for the Shuttle Orbiter vehicle during the ascent and re-entry phases of the flight and provides supplemental cooling to the radiators while on-orbit. This paper describes the design and operation of the FES and summarizes the operational flight experience to date. As the fleet of orbiters grows older, contamination and corrosion are two issues on which attention has focused. A discussion of these conditions and the subsequent design changes and operational workarounds will be summarized.

Spacecraft thermal control systems are essential to provide the necessary thermal environment for the crew and to ensure that the equipment functions adequately on space missions. The Ultralight Fabric Reflux Tube (UFRT) was developed by the Pacific Northwest National Laboratory as a lightweight radiator concept to be used on planetary surface-type missions (e.g., Moon, Mars). The UFRT consists of a thin-walled tube (acting as the fluid boundary), overwrapped with a low-mass ceramic fabric (acting as the primary pressure boundary). The tubes are placed in an array in the vertical position with the evaporators at the lower end. Heat is added to the evaporators, which vaporizes the working fluid. The vapor travels to the condenser end section and condenses on the inner wall of the thin-walled tube. The resulting latent heat is radiated to the environment. The fluid condensed on the tube wall is then returned to the evaporator by gravity.

The Early Human Testing Initiative (EHTI) Phase I Human Test, performed by the Crew and Thermal Systems Division at Johnson Space Center, demonstrated the ability of a crop of wheat to provide air revitalization for a human test subject for a 15-day period. The test demonstrated three different methods for control of oxygen and carbon dioxide concentrations for the human/plant system and obtained data on trace contaminants generated by both the human and plants during the test and their effects on each other. The crop was planted in the Variable Pressure Growth Chamber (VPGC) on July 24, 1995 and the test subject entered the adjoining airlock on day 17 of the wheat's growth cycle. The test subject stayed in the chamber for a total of 15 days, 1 hour and 20 minutes. Air was mixed between the plant chamber and airlock to provide oxygen to the test subject and carbon dioxide to the plants by an interchamber ventilation system.

A Total Organic Carbon (TOC) Analyzer has been developed for a Life Sciences Risk Mitigation Flight Experiment to be conducted on Spacehab and the Russian space station, Mir. Initial launch is scheduled for December 1996 (flight STS-81). The analyzer will be tested on the Orbiter in the Spacehab module, including when the Orbiter is docked at the Mir space station. The analyzer is scheduled to be launched again in May 1997 (STS-84) when it will be transferred to Mir. During both flights the analyzer will measure the quality of recycled and ground-supplied potable water on the space station. Samples will be archived for later return to the ground, where they will be analyzed for comparison to in-flight results. Water test samples of known composition, brought up with the analyzer, also will be used to test its performance in microgravity. Ground-based analyses of duplicates of those test samples will be conducted concurrently with the in-flight analyses.

We have conducted experiments on 16 lunar soils and 3 lunar volcanic glass samples to study the extraction of oxygen, an important resource for future lunar bases. The samples were chosen to span the range of composition and mineralogy represented in the Apollo collection. Each sample was reduced in flowing hydrogen for 3 hours at 1050°C. The dominant effect was reduction of Fe2+ (as FeO) in minerals and glass to iron metal, with concomitant release of oxygen. Oxygen extraction was strongly correlated with initial Fe2+ abundance but varied among mineral and glass phases. The experimental reduction of lunar soil and glass provides a method for assessing the oxygen production potential for sites on the lunar surface from lunar orbit. Our results show that oxygen yield from lunar soils can be predicted from knowledge of only one parameter, total iron content. This parameter can be measured from orbit by gamma ray spectrometry or multispectral imaging.

The incidence of decompression sickness (DCS) in space appears to be less than that predicted to occur on the basis of ground based altitude chamber trials. Our current work uses six hours of chair rest adynamia and likewise produces fewer gas bubbles when compared to standing in a cross over study. Mild exercise during oxygen prebreathe is also very efficacious in reducing DCS and bubble formation (measured by Doppler ultrasound). The effect is postulated to be the result of the alteration in the populations of tissue micronuclei such that the radii are reduced. Surface tension then becomes too great for bubble growth from the existing inert gas partial pressures.

This paper describes the process and analysis used to select a refrigerant and thermodynamic cycle as the basis of a vapor compression heat pump requiring a high temperature lift. Use of a vapor compression heat pump versus other types was based on prior work performed for the Electric Power Research Institute. A high lift heat pump is needed to enable a thermal control system to remove heat down to 275K from a habitable volume when the external thermal environment is severe. For example, a long term habitat will reject heat from a space radiator to a 325K environment. The first step in the selection process was to perform an optimization trade study, quantifying the effect of radiator operating temperature and heat pump efficiency on total system mass; then, select the radiator operating temperature corresponding to the lowest system mass. Total system mass included radiators, all heat pump components and the power supply system.

The incidence of DCS in null gravity appears to be considerably less than predicted by 1-g experiments. In NASA studies in 1-g, 83% of the incidents of DCS occur in the legs. We report first on a study with a crossover design that indicated a considerable reduction in the decompression Doppler bubble grade in the lower extremities in subjects in simulated microgravity (bed rest) as compared to themselves when ambulatory in unit gravity. Second we describe the results of a cardiovascular deconditioning study using a tail-suspended rat model. Since there may be a reduction in bubble production in 0-g, this would reduce the possibility of acquiring neurological DCS, especially by arterial gas embolism. Further, cardiovascular deconditioning appears to reduce the pulmonary artery hypertension (secondary to gas embolization) necessary to effect arterialization of bubbles.

Controlling microbial growth and biofilm formation in spacecraft water-distribution systems is necessary to protect the health of the crew. Methods to decontaminate the water system in flight may be needed to support long-term missions. We evaluated the ability of iodine and ozone to kill attached bacteria and remove biofilms formed on stainless steel coupons. The biofilms were developed by placing the coupons in a manifold attached to the effluent line of a simulated spacecraft water-distribution system. After biofilms were established, the coupons were removed and placed in a treatment manifold in a separate water treatment system where they were exposed to the chemical treatments for various periods. Disinfection efficiency over time was measured by counting the bacteria that could be recovered from the coupons using a sonication and plate count technique. Scanning electron microscopy was also used to determine whether the treatments actually removed the biofilm.

This ground-based study compared the risk of microbubbles during decompression under simulated space extravehicular activities (EVA) after three days of six-degree head-down bed rest with three days of ambulatory control. Test subjects were exposed to a pressure of 44.8 kPa (6.5 psi), breathed 100% oxygen, and exercised at reduced pressure either in the supine (during experimental) or upright (control) position. Circulating microbubbles were monitored by a precordial Doppler ultrasound device, and were found in 52% (12/23) of control and 26% (6/23) of experimental exposures. Survival analysis using Cox proportional hazards regression showed that there was 0.22 times (95% confidence interval=0.07-0.68) reduction in the risk of high grade microbubbles after bed rest, compared to controls (p=0.004). This finding is of importance in evaluating the risk of DCS during EVA.

Two simulated spacecraft water systems are being used to evaluate the effectiveness of iodine for controlling microbial contamination within such systems. An iodine concentration of about 2.0 mg/L is maintained in one system by passing ultrapure water through an iodinated ion exchange resin. Stainless steel coupons with electropolished and mechanically-polished sides are being used to monitor biofilm formation. Results after three years of operation show a single episode of significant bacterial growth in the iodinated system when the iodine level dropped to 1.9 mg/L. This growth was apparently controlled by replacing the iodinated ion exchange resin, thereby increasing the iodine level. The second batch of resin has remained effective in controlling microbial growth down to an iodine level of 1.0 mg/L. Scanning electron microscopy indicates that the iodine has impeded but may have not completely eliminated the formation of biofilm.